I have use 3mm marine plywood for several sea kayaks. It is easy to cut and sand. I would glass both sides to increase mechanical strength and prevent excess flexing but it should work fine. Probably should consider 1/2" to 3/4" thicknesses.
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I made a couple boats with 3/4" AC plywood...not marine ply...and have been sailing them for at least 5 or 6 years. The plywood can hold up to a lot of abuse. The only thing, is I believe it is somewhat heavier that spruce or fir or poplar would have been.
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